Catalytic Water Oxidation on Derivatized NanoITO
Electrocatalytic water oxidation occurs on high surface area, nanocrystalline ITO (nanoITO) surface-derivatized by phosphonate-binding of the catalyst [Ru(Mebimpy)(4,4'-((HO)(2)OPCH(2))(2)bpy)(OH(2))](2+) (Mebimpy is 2,6-bis(1-methylbenzimidazol-2-yl)pyridine; bpy is 2,2'-bipyridine). With nanoITO, spectral data can be acquired on electrochemically generated intermediates and voltammograms monitored spectrophotometrically..
Chen, Z., Concepcion, J., Hull, J., Hoertz, P., & Meyer, T. (2010). Catalytic Water Oxidation on Derivatized NanoITO. Dalton Transactions, 39(30), 6950 - 6952.